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Changes in the structure and properties of road bitumen during its thermal stabilization

https://doi.org/10.22227/1997-0935.2023.12.1926-1936

Abstract

Introduction. Petroleum bitumen is the main component of road surfaces, which play an important role in ensuring the safety and comfort of vehicle traffic. Over time, bitumen undergoes ageing, which leads to changes in its physical and chemical properties. Such changes cause a decrease in the quality of road surfaces, deterioration of their performance characteristics and reduction of durability. The analysis of research in the field of bitumen thermal stabilization, which is of great importance for optimization of technological processes at high temperatures, was carried out. The optimal composition of modified bitumen using stearic acid, industrial oil was determined.

Materials and methods. Bitumen undergoes serious changes during technological processes, during the transition from the bulk to the film state under the influence of high temperatures. Thus, thermal stability of bitumen is an important condition for preserving its quality at all stages of its life cycle. The issue of bitumen thermal stabilization with the use of stearic acid T-18 in combination with industrial oil I-20, which lead to increased resistance from external factors, is considered. To establish the degree of influence of modifying components on bitumen properties, a two-factor rotatable experiment with varying the amount of industrial oil and stearic acid additives, was performed.

Results. The compositions and properties of the obtained modified bitumen were studied. The analysis of the obtained results shows that the effect of stearic acid on bitumen penetration is about 6 times higher than the effect of industrial oil, while both components together have insignificant effect on the other studied properties of bitumen.

Conclusions. In order to further study thermal stability on the optimal versions of bitumen compositions, studies on mass retention of bitumen films at temperatures from 160 to 220 °C were performed. According to the obtained results, it was found that the effectiveness of stearic acid is manifested at higher temperatures and reaches values up to 25 %.

About the Authors

N. I. Shestakov
Moscow State University of Civil Engineering (National Research University) (MGSU)
Russian Federation

Nikolay I. Shestakov — Candidate of Technical Sciences, Associate Professor of the Department of Urban Planning

26 Yaroslavskoe shosse, Moscow, 129337

Scopus: 57205223447



N. V. Khokhlova
Moscow Automobile and Road College named after A.A. Nikolaev
Russian Federation

Natalia V. Khokhlova — postgraduate, lecturer of special disciplines

81 Bakuninskaya st., Moscow, 105082



Yu. E. Vasiliev
Moscow Automobile and Road State Technical University (MADI)
Russian Federation

Yuri E. Vasiliev — Doctor of Technical Sciences, Associate Professor, Head of of the Department of Road Construction Materials

64 Leningradsky prospect, Moscow, 125319

ID RSCI: 285866, Scopus: 57205604432, ResearcherID: I-8197-2013



U. O. Menkina
Moscow Automobile and Road State Technical University (MADI)
Russian Federation

Uliana O. Menkina — assistant, postgraduate student of the Department of Road Construction Materials

64 Leningradsky prospect, Moscow, 125319



References

1. Petrova L.M., Zajdullin I.M., Abbakumova N.A., Husnutdinov I.SH., Kashapova R.R. Informativeness of the parameters of the composition and structure of bitumen to assess their resistance to aging. Bulletin of Kazan Technological University. 2011; 10:131-134. EDN NXAIRD. (rus.).

2. Pechenyi B.G., Kurbatov V.L., Losev V.P. On the mechanism of bitumen aging and methods of their testing. University Science. 2019; 2(8):28-32. EDN NESZAL. (rus.).

3. Okhotnikova E.S., Ganeeva Y.M., Yusupova T.N., Romanov G.V., Frolov I.N. Express-method of determination of the content of resins and asphaltenes in bitumens by thermal analysis. International Journal of Applied Engineering Research. 2015; 10(24):44758-44763. EDN WPDVMB.

4. Ermolaev D.V., Mingaleeva G.R. Mechanism of thermal decomposition of asphaltenes of natural bitumen. Bulletin of the Technological University. 2015; 18(12):27-31. EDN UBLWFZ. (rus.).

5. Erofeev V.T., Likomaskina M.A., Afonin V.V., Arkhipova A.I. A study on resistance of asphalt concrete exposed to the effect of mycelial fungi. Vestnik MGSU [Monthly Journal on Construction and Architecture]. 2022; 17(10):1358-1371. DOI: 10.22227/1997-0935.2022.10.1358-1371 (rus.).

6. Shekhovtsova S., Korolev E. Interfacial phenomena at the interface in the system “Carbon Primary Materials-Water Solutions of Surfactants” for cement materials. Materials. 2022; 15(2):556. DOI: 10.3390/ma15020556

7. Inozemtcev S.S., Korolev E.V. Mineral carriers for nanoscale additives in bituminous concrete. Advanced Materials Research. 2014; 1040:80-85. DOI: 10.4028/www.scientific.net/amr.1040.80

8. Grengg C., Mittermayr F., Baldermann A., Böttcher M.E., Leis A., Koraimann G. et al. Microbiologically induced concrete corrosion: A case study from a combined sewer network. Cement and Concrete Research. 2015; 77:16-25. DOI: 10.1016/j.cemconres.2015.06.011

9. Radovsky B.S., Teltaev B.B. Viscoelastic characteristics of bitumen and their assessment by standard indicators. Highways. 2013; 8:50-60. (rus.).

10. Bulatović V.O., Rek V., Marković K.J. Effect of polymer modifiers on the properties of bitumen. Journal of Elastomers & Plastics. 2014; 46(5):448-469. DOI: 10.1177/0095244312469964

11. Teltayev B., Amirbayev E., Radovskiy B. Evaluating the Effect of Polymer Modification on the Low-Temperature Rheological Properties of Asphalt Binder. Polymers. 2022; 14(13):2548. DOI: 10.3390/polym14132548

12. Acevedo S., Castro A., Negrin J.G., Fernandez A., Escobar G., Piscitelli V. et al. Relations between asphaltene structures and their physical and chemical properties: The rosary-type structure. Energy & Fuels. 2007; 21(4):2165-2175. DOI: 10.1021/ef070089v

13. Rossi C.O., Caputo P., Ashimova S., Fabozzi A., D’Errico G., Angelico R. Effects of natural antioxidant agents on the bitumen aging process: An EPR and rheological investigation. Applied Sciences. 2018; 8(8):1405. DOI: 10.3390/app8081405

14. Zaidullin I.M., Petrova L.M., Yakubov M.R., Borisov D.N. Variation of the composition of asphaltenes in the course of bitumen aging in the presence of antioxidants. Journal of Applied Chemistry. 2013; 86(7):1137-1142. EDN AYVSZL. (rus.).

15. Ojum C., Kuna K., Thom N.H., Airey G.D. An investigation into the effects of accelerated curing on cold recycled bituminous mixes. Asphalt Pavements. 2014; 1177-1188. DOI: 10.1201/b17219-144

16. Shaban S.M. Effect of stearic acid on the mechanical properties and UV stability of LDPE. Journal of Applied Polymer Science. 2009; 113(4):2114-2122.

17. Kim S.K. Effect of stearic acid on the mechanical properties and thermal stability of polyamide 6. Journal of Applied Polymer Science. 2011; 119(6):3483-3490.

18. Lee K.S. Effect of stearic acid on the mechanical properties and thermal stability of polystyrene. Journal of Applied Polymer Science. 2011; 120(5):2705-2711.

19. Shirkunov A.S., Ryabov V.G., Kudinov A.V., Nechaev A.N., Degtyannikov A.S. Production of petroleum road bitumen with increased resistance against aging. Oil and Gas Studies. 2010; 5(83):89-94. EDN NTOHRJ. (rus.).

20. Opanasenko O.N., Luksha O.V., Zhigalova O.L., Krutko N.P., Chernetskaya V.M., Kozinets T.A. The effect of chemical modifiers’’ functional groups on the oil bitumen thermal stability. Proceedings of the National Academy of Sciences of Belarus. Chemical Series. 2015; 1:101-106. EDN TLCRLT. (rus.).

21. Shekhovtsova S.Yu., Vysotskaya M.A., Korolev E.V. Criterial estimation of thermal destructive processes in asphalt concrete on the basis of oxidized and residual bitumen. News of Higher Educational Institutions. Construction. 2018; 5(713):58-70. EDN XZOIJN. (rus.).


Review

For citations:


Shestakov N.I., Khokhlova N.V., Vasiliev Yu.E., Menkina U.O. Changes in the structure and properties of road bitumen during its thermal stabilization. Vestnik MGSU. 2023;18(12):1926-1936. (In Russ.) https://doi.org/10.22227/1997-0935.2023.12.1926-1936

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ISSN 1997-0935 (Print)
ISSN 2304-6600 (Online)