Hydration of cement binders with mineral additives based on clay and carbonate rocks
https://doi.org/10.22227/1997-0935.2024.8.1317-1327
Abstract
Introduction. The use of mineral additives in cement concrete compositions makes it possible to reduce the consumption of Portland cement, which, with increasing construction rates, reduces the negative impact on the environment during its production. However, the high cost and territorial limitation of the production of the most effective modifiers (microsilica, metakaolin) do not allow to satisfy the growing demand for them. The development of mineral additives from widely used raw materials will help solve the problem of the deficit of the most common additives, as well as to reduce the consumption of Portland cement. The mechanism of hardening of Portland cement with widespread mineral additives was studied in sufficient detail. At the same time, there are practically no works describing the processes of hydration of cement binder modified with mineral additives based on thermally activated clay and carbonate rocks.
Materials and methods. The following mineral additives were used: thermally activated clay (Nikitskoye deposit, Saransk, Republic of Mordovia), dolomite (Elniki village, Republic of Mordovia), thermally activated mixture of clay and limestone (Atemar village, Republic of Mordovia). Using the method of X-ray phase analysis, the mechanisms of action of these mineral additives on hydration processes are considered.
Results. It was established that the use of these mineral additives makes it possible to increase the degree of hydration of Portland cement and change the phase composition of the cement stone in a targeted manner.
Conclusions. The data obtained indicate the prospects and relevance of the direction for the development of concretes with modifying additives based on thermally activated polymineral clays and carbonate rocks, which makes it possible to expand the range of modified cement composites produced today due to more complete use of the local mineral resource base.
About the Authors
V. V. Volodin
Ogarev Mordovia State University
Russian Federation
Russian Federation
Vladimir V. Volodin — Candidate of Technical Sciences, research engineer of the Research Laboratory of Ecological and Meteorological Monitoring, Construction Technologies and Expertise
68 Bolshevistskaya st., Saransk, 430005
RSCI AuthorID: 933723, Scopus: 57195424982, ResearcherID: ААН-7738-2020
O. V. Tarakanov
Penza State University of Architecture and Construction (PGUAS)
Russian Federation
Russian Federation
Oleg V. Tarakanov — Doctor of Technical Sciences, Professor, Dean of the Faculty of Territorial Management
28 German Titov st., Penza, 440028
RSCI AuthorID: 448093, Scopus: 7004757888
T. A. Nizina
Ogarev Mordovia State University
Russian Federation
Russian Federation
Tat’yana A. Nizina — Doctor of Technical Sciences, Professor of the Department of Building Structures
68 Bolshevistskaya st., Saransk, 430005
RSCI AuthorID: 131099, Scopus: 57190161363, ResearcherID: Р-2639-2017
V. M. Kyashkin
Ogarev Mordovia State University
Russian Federation
Russian Federation
Vladimir M. Kyashkin — Candidate of Physical and Mathematical Sciences, Associate Professor, Senior Researcher of the Department of Physical Materials Science
68 Bolshevistskaya st., Saransk, 430005
RSCI AuthorID: 27869, Scopus: 7801669853, ResearcherID: AAE-1757-2019
A. S. Balykov
Ogarev Mordovia State University
Russian Federation
Russian Federation
Artemiy S. Balykov — Candidate of Technical Sciences, Senior Researcher of the Research Laboratory of Ecological and Meteorological Monitoring, Construction Technologies and Expertise
68 Bolshevistskaya st., Saransk, 430005
RSCI AuthorID: 813269, Scopus: 57190170885, ResearcherID: AAF-4208-2020
References
1. Khozin V.G., Khokhryakov O.V., Sibgatullin I.R. “Carbonate” cements of low water demand. Moscow, ASV, 2021; 366. (rus.).
2. Kaprielov S.S., Sheinfeld A.V., Dondukov V.G. Cements and additives for producing high-strength concretes. Construction Materials. 2017; 11:4-10. EDN ZWUFVB. (rus.).
3. Kalashnikov V.I., Tarakanov O.V., Kusne-tsov Y.S., Volodin V.M., Belyakova E.A. Next generation concrete on the basis of fine-grained dry powder mixes. Magazine of Civil Engineering. 2012; 8(34):47-53. EDN PJWLHF. DOI: 10.5862/mce.34.7. (rus.).
4. Tarakanov O.V., Belyakova E.A., Yurova V.S. On the issue of expanding the base of mineral and complex additives for cement concrete. E3S Web of Conferences. 2019; 135:01018. DOI: 10.1051/e3sconf/201913501018
5. Tarakanov O.V., Belyakova E.A., Yurova V.S. Complex organomineral additives with hardening accelerator. Solid State Phenomena. 2018; 284:929-935. DOI: 10.4028/www.scientific.net/ssp.284.929
6. Nizina T.A., Balykov A.S., Volodin V.V., Korovkin D.I. Fiber fine-grained concretes with polyfunctional modifying additives. Magazine of Civil Engineering. 2017; 4(72):73-83. DOI: 10.18720/MCE.72.9. EDN ZFCAMF.
7. Nizina T.A., Balykov A.S., Korovkin D.I., Volodin V.V. Physical and mechanical properties of modified fine-grained fibre-reinforced concretes containing carbon nanostructures. International Journal of Nanotechnology. 2019; 16(6/7/8/9/10):496. DOI: 10.1504/ijnt.2019.106621
8. Bazhenov Y.M. Concrete science : textbook. Moscow, ASV Publishing House, 2015; 144. (rus.).
9. Nguyen Doan Tung Lam, Samchenko S.V. Complex modifier based on alumina cement and pozzolanic addition. Vestnik MGSU [Monthly Journal on Construction and Architecture]. 2023; 18(5):709-716. DOI: 10.22227/19970935.2023.5.709-716 (rus.).
10. Lam N.D.T., Samchenko S.V., Shvetsova V.A., Bulgakov B.I. Influence of complex additives on the strength of cement stone at an early age. Industrial and Civil Engineering. 2023; 5:52-59. DOI: 10.33622/0869-7019.2023.05.52-59. EDN PFYHXG. (rus.).
11. Butt Y.M. Technology of cement and other binders. Moscow, Stroyizdat Publ., 1976; 407. (rus.).
12. Habert G., Choupay N., Escadeillas G., Guillaume D., Montel J.M. Clay content of argillites: Influence on cement based mortars. Applied Clay Science. 2009; 43(3-4):322-330. DOI: 10.1016/j.clay.2008.09.009
13. Schulze S.E., Rickert J. Pozzolanic activity of calcined clays. SP-289: Twelfth International Conference on Recent Advances in Concrete Technology and Sustainability Issues. 2012.
14. Fernandez R., Martirena F., Scrivener K.L. The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite. Cement and Concrete Research. 2011; 41(1):113-122. DOI: 10.1016/j.cemconres.2010.09.013
15. Rakhimov R.Z., Kamalova Z.A., Yermilova E.Y. Blended portland cement based on thermally activated clays and carbonate additives. Inorganic Materials: Applied Research. 2018; 9(4):578-583. DOI: 10.1134/s2075113318040329
16. Balykov A.S., Nizina T.A., Volodin V.V., Kyashkin V.M. Effects of calcination temperature and time on the physical-chemical efficiency of thermally activated clays in cement systems. Materials Science Forum. 2021; 1017:61-70. DOI: 10.4028/www.scientific.net/msf.1017.61
17. Nizina T., Balykov A., Volodin V., Kyashkin V. Structure and properties of cement systems with additives of calcined clay and carbonate rocks. Magazine of Civil Engineering. 2022; 8(116):11602. DOI: 10.34910/MCE.116.2. EDN XFXNAO.
18. Volodin V.V., Nizina T.A. Analysis of the mineral raw material base of the republic of Mordovia suitable for the production of active mineral additives. Expert: Theory and Practice. 2023; 1(20):59-62. DOI: 10.51608/26867818_2023_1_59. EDN ZBEXPG. (rus.).
19. Taylor H.F. Chemistry of cements. Moscow, Mir Publ., 1996; 529. (rus.).
20. Gorshkov V.S., Timashev V.V., Savelyev V.G. Methods of physical and chemical analysis of binders : textbook. Moscow, Higher School Publ., 1981; 335. (rus.).
21. Sheinfeld A.V., Kaprielov S.S., Chilin I.A. Influence of temperature on the parameters of the structure and properties of cement systems with organo-mineral modifiers. Urban planning and architecture. 2017; 7(1):58-63. DOI: 10.17673/Vestnik.2017.01.10. EDN YRDUEV. (rus.).
22. Detwiler R.J., Mehta P.K. Chemical and physical effects of silica fume on the mechanical behavior of concrete. ACI Materials Journal. 1989; 86(6):609-614. DOI: 10.14359/2281
Review
For citations:
Volodin V.V., Tarakanov O.V., Nizina T.A., Kyashkin V.M., Balykov A.S. Hydration of cement binders with mineral additives based on clay and carbonate rocks. Vestnik MGSU. 2024;19(8):1317-1327. (In Russ.) https://doi.org/10.22227/1997-0935.2024.8.1317-1327
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