Study of the mechanism of photocatalytic activity of zinc oxide in the presence of synthetic zeolite
https://doi.org/10.22227/1997-0935.2024.11.1758-1769
Abstract
Introduction. The regularities of changes in the photocatalytic activity of zinc oxide ZnO in the presence of synthetic zeolite are investigated. The data on the photocatalytic properties of the surface of lime coating based on the composition with the addition of zinc oxide and synthetic zeolite are presented.
Materials and methods. A complex of general scientific research methods was used. Lime with activity of 83 % was used in the development of the formulation of the finishing composition. An aluminosilicate additive was used as a synthetic zeolite, obtained by adding microdispersed aluminum powders to sodium liquid glass with silicate module of 2.9 at a temperature of 60 °C for 90 minutes. The photocatalytic activity of ZnO using synthetic zeolite was studied by photodegradation of methylene blue dye under the action of UV light. The methods presented in the scientific and technical literature were used. Spectroscopic studies of the specimens were carried out on an FSM 1201 IR Fourier spectrometer (LLC “Infraspek”, Russia) and an SF-56 spectrophotometer.
Results. An increase in the photocatalytic properties of the surface of a lime coating based on a composition using ZnO oxide and synthetic zeolite was established. The optical band gap of ZnO was determined. It was revealed that the optical band gap of zinc oxide in combination with synthetic zeolite is 2.96 and 2.70 eV, which is significantly less than the value of 3.37 eV characteristic of zinc oxide.
Conclusions. To impart self-cleaning properties to lime coatings, it is proposed to introduce zinc oxide into the formulation of the photocatalyst together with an additive based on synthetic zeolite.
About the Authors
V. I. Loganina
Penza State University of Architecture and Construction (PSUAC)
Russian Federation
Russian Federation
Valentina I. Loganina — Doctor of Technical Sciences, Professor, Head of the Department of Quality Management and Construction Production Technologies
28 German Titov st., Penza, 440028
RSCI AuthorID: 369481, Scopus: 6602801860, ResearcherID: N-5558-2015
A. D. Ryzhov
Penza State University of Architecture and Construction (PSUAC)
Russian Federation
Russian Federation
Anton D. Ryzhov — senior lecturer of the Department of Information and Computing Systems
28 German Titov st., Penza, 440028
RSCI AuthorID: 818457, Scopus: 56500199300
I. A. Pronin
Penza State University
Russian Federation
Russian Federation
Igor A. Pronin — Doctor of Technical Sciences, Professor, Head of the Department of Nano- and Microelectronics
40 Krasnaya st., Penza, 440026
A. A. Karmanov
Penza State University
Russian Federation
Russian Federation
Andrej A. Karmanov — Candidate of Technical Sciences, Associate Professor, Associate Professor of the Department of Nano- and Microelectronics
40 Krasnaya st., Penza, 440026
RSCI AuthorID: 652871, Scopus: 55597544400, ResearcherID: S-5175-2016
N. D. Yakushova
Penza State University
Russian Federation
Russian Federation
Nadezhda D. Yakushova — Candidate of Technical Sciences, Associate Professor of the Department of Nano- and Microelectronics
40 Krasnaya st., Penza, 440026
References
1. Tolstoy A.D., Lesovik V.S., Glagolev E.S., Vodopyanov I.O. Self-restoration hardening systems of high-strength concrete of a new generation. IOP Conference Series: Materials Science and Engineering. 2019; 560(1):012156. DOI: 10.1088/1757-899x/560/1/012156
2. Falikman V.R., Vainer A.Ya. New high performance nanoadditives for photocatalytic concrete: synthesis and study. Nanotechnologies in Construction: A Scientific Internet-Journal. 2015; 7(1):18-28. DOI: 10.15828/2075-8545-2015-7-1-18-28. EDN TIXUVD. (rus.).
3. Lukuttsova N.P., Postnikova O.A., Soboleva G.N., Rotar’ D.V., Ogloblina E.V. Photo-catalytic pavement on the basis of additive of nano-disperse titanium dioxide. Construction Materials. 2015; 11:5-8. EDN VCIDUF. (rus.).
4. Falikman V.R. Photocatalytically active building materials with titanium dioxide nanoparticles — a new concept for improving the ecology of megacities. Moscow, MGSU, 2015; 49. (rus.).
5. Kiriakidou F., Kondarides D.I., Verykios X.E. The effect of operational parameters and TiO2-doping on the photocatalytic degradation of azo-dyes. Catalysis Today. 1999; 54(1):119-130. DOI: 10.1016/s0920-5861(99)00174-1
6. Umebayashi T., Yamaki T., Itoh H., Asai K. Analysis of electronic structures of 3d transition metal-doped TiO2 based on band calculations. Journal of Physics and Chemistry of Solids. 2002; 63(10):1909-1920. DOI: 10.1016/s0022-3697(02)00177-4
7. Stepanov A.Yu., Sotnikova L.V., Vladimirov A.A., Dyagilev D.V., Larichev T.A., Pugachev V.M. et al. Synthesis and research of photocatalytic properties of TiO2 based materials. Bulletin of Kemerovo State University. 2013; 2-1(54):249-255. EDN OLMIVS. (rus.).
8. Samchenko S.V., Kozlova I.V., Korshunov A.V., Zemskova O.V., Dudareva M.O., Agafonova N.Z. Investigation of physico-mechanical and photocatalytic properties of cement composites modified with industrial titanium dioxide. Technique and Technology of Silicates. 2023; 30(2):152-161. EDN LFEMUW. (rus.).
9. Kozlova I.V., Zemskova O.V., Samchenko S.V., Dudareva M.O. Methods of synthesis of a photoctalytic additive for cement systems. Technique and Technology of Silicates. 2023; 30(3):206-216. EDN HJAAJE. (rus.).
10. Samchenko S.V., Kozlova I.V., Korshunov A.V., Zemskova O.V., Dudareva M.O. Synthesis and Evaluation of Properties of an Additive Based on Bismuth Titanates for Cement Systems. Materials. 2023; 16(18):6262. DOI: 10.3390/ma16186262
11. Lashkova N.A., Maximov A.I., Ryabko A.A., Bobkov A.A., Moshnikov V.A., Terukov E.I. Synthesis of ZNO-based nanostructures for heterostructure photovoltaic cells. Semiconductors. 2016; 50(9):1276-1282. EDN XAXUWV. (rus.).
12. Averin I.A., Pronin I.A., Yakushova N.D., Karmanov A.A., Moshnikov V.A., Sychev M.M. et al. Analysis of the structural evolution of zinc oxide powders obtained by mechanical high-energy grinding. Technical Physics. 2019; 89(9):1406-1411. DOI: 10.21883/JTF.2019.09.48067.437. EDN OHCSAR. (rus.).
13. Nikazar M., Alizadeh M., Lalavi R., Rostami M.H. The optimum conditions for synthesis of Fe3O4/ZnO core/shell magnetic nanoparticles for photodegradation of phenol. Journal of Environmental Health Science and Engineering. 2014; 12(1). DOI: 10.1186/2052-336x-12-21
14. Elshypany R., Selim H., Zakaria K., Moustafa A.H., Sadeek S.A., Sharaa S.I. et al. Elaboration of Fe3O4/ZnO nanocomposite with highly performance photocatalytic activity for degradation methylene blue under visible light irradiation. Environmental Technology & Innovation. 2021; 23:101710. DOI: 10.1016/j.eti.2021.101710
15. Gubareva E.N., Baskakov P.S., Strokova V.V., Labuzova M.V. Features of the structure of sols of titanium dioxide and morphology of the films based on them. News of the St. Petersburg State Technological Institute (Technical University). 2019; 48(74):78-83. EDN KFLTUQ. (rus.).
16. Zhang J., Liu Z. Fabrication and characterization of Eu2+-doped lanthanum-magnesium-gallium/TiO2-based composition as photocatalytic materials for cement concrete-related methyl orange (MO) degradation. Ceramics International. 2019; 45(8):10342-10347. DOI: 10.1016/j.ceramint.2019.02.090
17. Sreethawong T., Suzuki Y., Yoshikawa S. Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol-gel process with surfactant template. International Journal of Hydrogen Energy. 2005; 30(10):1053-1062. DOI: 10.1016/j.ijhydene.2004.09.007
18. Li G., Mang C., Xing L., Cao P., Cai Y., Luo J. et al. Surfactant-assisted synthesis of Mo-doped TiO2/FAC (fly ash cenosphere) for degradation of methylene blue dye under visible light irradiation. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2022; 651:129669. DOI: 10.1016/j.colsurfa.2022.129669
19. Yan Y., Li C., Wu Y., Gao J., Zhang Q. From isolated Ti-oxo clusters to infinite Ti-oxo chains and sheets: Recent advances in photoactive Ti-based MOFs. Journal of Materials Chemistry A. 2020; 8(31):15245-15270. DOI: 10.1039/d0ta03749d
20. Cheng W., Li C., Ma X., Yu L., Liu G. Effect of SiO2-doping on photogenerated cathodic protection of nano-TiO2 films on 304 stainless steel. Materials & Design. 2017; 126:155-161. DOI: 10.1016/j.matdes.2017.04.041
21. Liu W., Li C., Mao J., Hu L., Li M., Yun Y. et al. Synergistic effect of xSi-TiO2 ceramic membrane on photocatalytic oxidation and water vapor recovery of high humidity NO. Separation and Purification Technology. 2023; 318:123928. DOI: 10.1016/j.seppur.2023.123928
22. Viezbicke B.D., Patel S., Davis B.E., Birnie D.P. Evaluation of the Tauc method for optical absorption edge determination: ZnO thin films as a model system. Physica status solidi (b). 2015; 252(8):1700-1710. DOI: 10.1002/pssb.201552007
23. Loganina V.I., Ryzhov A.D. Structure and pro-perties of synthesized additive based on amorphous aluminosilicates. Case Studies in Construction Materials. 2015; 3:132-136. DOI: 10.1016/j.cscm.2015.10.005
24. Loganina V.I., Ryzhov A.D. Properties of limy composites with the addition aluminosilicates. Contemporary Engineering Sciences. 2015; 8:409-413. DOI: 10.12988/ces.2015.5237
25. Loganina V.I., Skachkov Y.P., Ryzhov A.D. Additive based on aluminosilicates for lime dry mortar mixes. IOP Conference Series: Materials Science and Engineering. 2018; 441:012028. DOI: 10.1088/1757-899x/441/1/012028
26. Loganina V.I., Makarova L.V., Tarasov R.V., Ryzhov A.D. The limy composite binder with the use of the synthesized aluminosilicates. Applied Mechanics and Materials. 2014; 662:11-14. DOI: 10.4028/www.scientific.net/amm.662.11
27. Ellerbrock R., Stein M., Schaller J. Comparing amorphous silica, short-range-ordered silicates and silicic acid species by FTIR. Scientific Reports. 2022; 12(1). DOI: 10.1038/s41598-022-15882-4
Review
For citations:
Loganina V.I., Ryzhov A.D., Pronin I.A., Karmanov A.A., Yakushova N.D. Study of the mechanism of photocatalytic activity of zinc oxide in the presence of synthetic zeolite. Vestnik MGSU. 2024;19(11):1758-1769. (In Russ.) https://doi.org/10.22227/1997-0935.2024.11.1758-1769
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